The Reasons for Drying Hygroscopic Resins
The reason you dry certain plastic shredder
is to get the moisture out. But why does the moisture have to be taken
out before processing? Even though some chemistry is involved, we are
going to explain this with the analogy of tiny magnets. Everybody
understands magnets.
First: Plastics get their strength from
long polymer chains that are entangled. Short chains provide easier flow
but sacrifice strength and other properties.
Second: Some Plastics
pull moisture out of the air. They are “hygroscopic.” Even if your
material supplier dries the pellets and immediately packs them in plastic recycling machine,
the resin will still contain moisture when you get them. Why? Because
polyethylene-based bags do not block the moisture in the air from
getting to the pellets. Polyethylene by itself is not a true “barrier”
resin; it is “porous” to moisture vapor (humidity).
Third: Why
are some resins hygroscopic in the first place? Polycarbonate, nylon,
PBT, PET, ABS, acrylic, urethanes, and many other hygroscopic resins are
long-chain polymers, as are polyethylene, polystyrene, etc. Hygroscopic
resins contain carbon and hydrogen but, also have a “polar” segment of
atoms that behave like a small magnet with north and south poles—i.e.,
positive and negative charges. If moisture, also a polar substance, is
present, you get two mini-magnets that attract each other.
Fourth:
Some moderately hygroscopic resins like ABS and acrylic can be
processed wet, but the moisture will turn to steam and cause splay. The
moisture does not break up the backbone of these polymers. With other
resins—like PET, PBT, PC, nylon, and plastic crusher
to moisture at processing temperature causes a chemical reaction
(hydrolysis), which breaks long chains into shorter fragments, reducing
strength and other properties. The “broken” polymer also flows easier,
so if the polymer is not uniformly dried, your process must contend with
variation in viscosity of the incoming resin at the feed throat. There
may be no splay visible at low levels of moisture in the resin. The part
will look fine and may even pass tests at room temperature, but will
fail prematurely at low or high temperatures.
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